Molecular Weight (g/mol) 298.00: CAS-No. Plastics without additives are not viable. Atlanta, GA 30318, according to Regulation (EC) No 1907/2006 (REACH), IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING, Relevant identified uses of the substance or mixture, 2.1 Classification of the substance or mixture, 6.1 Personal precautions, protective equipment and emergency procedures, 9.1 Information on basic physical and chemical properties, 11.1 Information on toxicological effects. Item List Price (USD) Size This is the first book to consolidate the current state of the art information on natural rubber based materials providing a "one stop" reference resource for professionals, researchers, industrial practitioners, graduate students, and ... 6PPD-quinone is a major contributor to the "urban runoff mortality syndrome" that kills 40 - 90% of returning salmon before spawning. 6PPD-Quinone • Transformation material of 6PPD, identified for the . Molecular Weight (g/mol) 303.41: CAS-No. 6PPD-QUINONE (PHENYL-13C6, 99%) 100 UG/ML IN ACETONITRILE. C18H22N2O2. It is found in soil and foods such as kiwifruit, as well as human breast Sulfide: quinone reductase EC 1.8.5.4 is an enzyme with systematic name sulfide: quinone . <> Additional Data Labeled CAS# NA. Found inside – Page iiThis book introduces the chemistry of aromatics with a brief discussion of the aromatic character and a survey of historical aspects, particularly the development of the organic dye industry during the 19th century. ULM-12288-1.2. Found insideUrban Climates is the first full synthesis of modern scientific and applied research on urban climates. The book begins with an outline of what constitutes an urban ecosystem. 10243 6PPD-quinone Synonym 2-anilino 5 (1,3 dimethylbutylamino) 1,4 benzoquinone CAS-No Molecular Formula C 18 H 22 N 2 O 2 Formula Weight 298.38 InChI Key UBMGKRIXKUIXFQ-UHFFFAOYSA-N Item no. sales@hpc-standards.us This book is dedicated to providing the reader with various experimental ideas which may guide him or her to developing better compounds and solving technical problems. 6-PPD is a chemical widely veteran to offer protection to vehicle tires from ozone. Prevent, 9.1 Information on basic physical and chemical properties, 11.1 Information on toxicological effects, 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture, The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. Environmental relevance of 6PPD-quinone. �H�0� <>/ExtGState<>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> Item Number. This is the first volume of a two-volume work which summarizes in an edited format and in a fairly comprehensive manner many of the recent technical research accomplishments in the area of Elastomers. “Advances in Elastomers” discusses ... For decades, scientists have worked to pin down what causes mass . Now, the team can start to understand why this chemical is so toxic. by Tian et al. 2005; Tian et al. Found inside... 1 – thermogravimetric analysis 1 Moleculart weight (MW) modifiers 1 Molecular weight distribution (MWD) 1 Monoclonal ... (6PPD) 1, 2, 3, 4 N-(1,3-dimethylbutyl)-Nʹ-phenyl-1,4-p-benzoquinone diimine 1 N-(2,2-dimethylpropyl)-N-methyl ... "We believe that 6PPD-quinone is the primary causal toxicant for these observations of coho salmon mortality in the field," said Ed Kolodziej, the lead investigator for this study. Molecular Weight* 298.39. Researchers from Northeastern College and the College of Washington realized that even tiny doses of . Skin contact: Remove/Take off immediately all contaminated clothing. In case of skin contact The key factor that contributes to the deaths is a chemical antioxidant known as 6PPD, which is used in tires to make them last longer; however, according to scientists, the 6PPD in the bits of tires left on the roads react with ozone to become a byproduct called 6PPD-quinone. Recently, a quinone oxidation by-product of the tire additive, N-phenyl-N'- (1,3-dimethylbutyl)-p-phenylenediamine (6PPD) was identified as a compound that is acutely toxic to salmon and this 6PPD-quinone (6PPD-q) compound was detected in urban road runoff and in surface waters ( Tian et al., 2021) Found inside – Page iRubber analysis plays a vital part in ensuring that manufactured products are fit for purpose. Other important examples are 1,2-benzoquinone (ortho-quinone), 1,4-naphthoquinone and 9,10-anthraquinone Properties. The density is 1.32-1 Soluble in . Product Name Price range Estimated delivery; TR-P348790 6PPD-quinone | Applications 6PPD-quinone is a derivative of 2-Amino-5-anilino-1,4-benzoquinone, which is useful in hair dye compositions. The oxida-tion by-product of 6PPD was identied as a likely candi-date compound causing mass mortalities of coho salmon 2021). 6-PPD is a chemical widely used to protect car tires from ozone. Unlabeled CAS# NA. Property Name Property Value Reference; Molecular Weight: 298.4: Computed by PubChem 2.1 (PubChem release 2021.05.07) XLogP3-AA: 4.1: Computed by XLogP3 3.0 (PubChem release 2019.06.18) FIRST AID MEASURES: 4.1 Description of first aid measures General advice Consult a physician. References. But when 6PPD reacts with ozone, the researchers found that it is transformed into multiple chemicals, including 6PPD-quinone. The 6PPD in the plastic bits reacts with ozone to become another chemical: a previously unreported substance called 6PPD-quinone. In composite samples collected at intervals throughout one rain . Sunboss Chemicals Corp. / MSDS for 6PPD Page 4 pH Not applicable Other Solubility Soluble in acetone, ethanol, benzene, naphtha Boiling point 441°F/227°C @ 4Torr Melting Point 115-124°F/45-51°C Molecular Weight 268.4 Molecular Formula C 18-H 24-N 2 10. found that 6PPD, the primary antioxidant chemical used in tire rubber, reacts with ozone to form the previously unidentified compound 6PPD-quinone. ڒ��� ����'b�l.g��b��=�3��ק�b�d������'� (A) Using retrospective UPLC-HRMS analysis of archived sample extracts, 6PPD-quinone was quantified in roadway runoff and runoff-impacted receiving waters. In a weight-of-evidence approach using an experimental study for a higher homologue of the parephenylenediamines ("8PPD") which resulted in a BCF of 1700 and supporting information from a QSAR for 8PPD the result of BCF 568.7 for 6PPD was validated. Quinones are oxidized derivatives of aromatic compounds and are often readily made from reactive aromatic compounds with electron-donating substituents such as phenols and catechols, which . <> Found insideThis book will be of vital interest to students, practitioners, and research and development managers, as well as to anyone interested in the unusual chemistry and physics and the outstanding properties and usefulness of elastomers. Nearly all tires worldwide contain 6PPD and shed the toxic 6PPD-quinone. Looking more broadly, there is the obvious question about the impact 6-PPD quinone may have on other freshwater species - it seems unlikely that such toxic effects would be limited to salmonids. Found insideA stable usage of rubber compounds in the production of components for almost every industry has created the need for this handbook and formulary. The confirmed presence of 6PPD-quinone in California's waterways threatens the state's remaining coho salmon populations, which are endangered or threatened, and may jeopardize the recovery of this species. (A) Using retrospective UPLC-HRMS analysis of archived sample extracts, 6PPD-quinone was quantified in roadway runoff and runoff-impacted receiving waters.Each symbol corresponds to duplicate or triplicate samples, boxes represent first and third quartiles. in December 2020. It's 2-anilino-5-([4-methylpentan-2-yl]amino)cyclohexa-2,5-diene-1,4-dione, or 6PPD-quinone for short. 6PPD and 6PPD-Quinone - two distinct materials 6PPD • Antioxidant and antiozonant - protects tires during both static and dynamic conditions • Minimizes thermal degradation . However, when rainwater washes it into freshwater, 6PPD degrades into 6-PPD quinone, a contaminant that a recent study has linked to the mass deaths of Coho salmon in the Pacific Northwest of the US. Properties: Pure 6PPD is white solid product, and will gradually oxidizing to brown solid when exposed to the air.Industrial product—6PPD is purple brown to black brown granules or flakes, and will slowly caking When the temperature exceeds 35-40℃.Soluble in gasline, benzene, acetone, ethyl acetate, dichloroethane, carbon tetrachloride ,methylbenzene, ethylalcohol and other organic . 1170 Howell Mill Road, Suite 300 Properties: Pure 6PPD is white solid product, and will gradually oxidizing to brown solid when exposed to the air.Industrial product—6PPD is purple brown to black brown granules or flakes, and will slowly caking When the temperature exceeds 35-40℃.Soluble in gasline, benzene, acetone, ethyl acetate, dichloroethane, carbon tetrachloride ,methylbenzene, ethylalcohol and other organic . endobj Nonetheless, when rainwater washes it into freshwater, 6PPD degrades into 6-PPD quinone, a contaminant that a most fresh ogle has linked to the mass deaths of Coho salmon in the Pacific Northwest of the US.. * "Coho are enormous and brightly colored, so people can readily see them suffering," says Sutton, but salmon's troubles could signal broader, systemic problems. That 6PPD then converts into . A valid QSAR for the BCF of 6PPD was used yielding a BCF of 568.7. No one manufactures it. Researchers blame a newly identified compound, 6PPD-quinone, for acute die-offs of coho salmon. Here, the author has compiled data on about 550 oil-bearing plant species with respect to their content of unsaponifiable matters and oils. Chemical Formula. It has a role as a water-soluble vitamin and a cofactor.It is a member of orthoquinones, a tricarboxylic acid and a pyrroloquinoline cofactor. It starts with a chemical antioxidant known as 6PPD, used in tires around the world to make them last longer. For comparison, the 0.8 μg/L LC50 value for juvenile coho salmon and detected 6PPD . In addition, extracts were analyzed for 1,3 . 2 0 obj Found insideThe Handbook of Environmental Degradation of Materials explains how to measure, analyse, and control environmental degradation for a wide range of industrial materials including metals, polymers, ceramics, concrete, wood and textiles ... 5 Quinone exists as yellow prisms, with a penetrating odor resembling that of chlorine. x��]m��6���*�n]]��� ��J���fc��%���ʌ�H (R�l����Fw�@��lw���]��7���v����e���盏�||�������j�ح6���?��ß^-�����&O��&O�>x��%���H�?���-T���-�y�^'Wwd��Uؿ^>|��Y2�gr�����m�z��LJ��7���W:y��4I��f�9}�,��װ2K�J�,Ӳ�Y6g*����2^�(z�: a�� ?ש��^ L��TB�,Os�H�S�'y���]>|��5�m��-�vU�j�=O�LK����)�P]��� �7 �H}6��(��M�����e�/s&�%'z�l�[$����r~"gP�8���mI�Ə�.� Get Price FIRST AID MEASURES: 4.1 Description of first aid measures Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing. CLM-12293-1.2. But in the mass die-off autumn events along the West Coast, 40 percent to 90 percent of the salmon have died.""It is unlikely 6PPD-quinone is toxic only to coho salmon, the researchers said, but . Retrospective analysis of representative roadway runoff and stormwater-impacted creeks of the U.S. West Coast indicated widespread occurrence of 6PPD-quinone (<0.3-19 μg/L) at toxic . By mixing the antidegradant quinone diimine with the elastomer prior to vulcanization, enhanced handling and processing qualities are realized in the vulcanized rubber. You're not alone. 3 0 obj In a weight-of-evidence approach using an experimental study for a higher homologue of the parephenylenediamines ("8PPD") which resulted in a BCF of 1700 and supporting information from a QSAR for 8PPD the result of BCF 568.7 for 6PPD was validated. McIntyre, an assistant professor of aquatic toxicology at Washington State University , observed how a coho salmon would breathe erratically and struggle to stay upright when exposed to 6PPD-quinone. �@��תM�YU7{�_Go Wear suitable protective equipment. Found insideThis book provides a modern and easy-to-understand introduction to the chemical equilibria in solutions. Researchers from Northeastern University and the University of Washington found that even small doses of 6PPDq were lethal for the . However, as tire treads break down over time and leave behind bits of microplastics on roads, the 6PPD in them reacts with ozone to become a different chemical -- a previously unreported byproduct called 6PPD-quinone, scientists say. The killer was the 6PPD-quinone from the tires in the roadway runoff. 6PPD is an organic chemical used as an antiozonant in rubber tires. According to the authors, 6PPD . Its main application was as a stabilizer compound in common solvents such as TCA, and was used to enhance solvent life and prevent decomposition from light, heat, oxygen, and acids. According to the authors, 6PPD-quinone is highly toxic and is deadly to juvenile salmon at concentrations of roughly 1 microgram per liter. Prompted by a recent report that 6PPD-quinone (6PPD-q), a by-product of a common tire manufacturing additive that is present in road runoff, is toxic to coho salmon (Oncorhynchus kisutch), extracts of water samples collected from an urban river were re-analyzed to determine if this compound was present in stormwater-influenced flows. However, when rainwater washes it into freshwater, 6PPD degrades into 6-PPD quinone, a contaminant that a recent study has linked to the mass deaths of Coho salmon in the Pacific Northwest of the US.. Item no. (6) The chemical formula for quinone is C 6 H 4 O 2, and the molecular weight is 108.1 g/mol. As tiny pieces of tire break off on roads and highways, the preservative 6PPD interacts with ground-level ozone to create 6PPD-quinone, which in turn washes into creeks and rivers when it rains . A quinone methide is a type of conjugated organic compound that contain a cyclohexadiene with a carbonyl and an exocyclic methylene group or extended Pyrroloquinoline quinone PQQ also called methoxatin, is a redox cofactor. 6PPD-quinone is an oxidation product of 6PPD, an industrial antioxidant compound commonly used in tires. Tian et al. Unlabeled CAS# NA. [6] Coho salmon in the Pacific Northwest are listed as threatened under the ESA and researchers believe it is unlikely that coho are uniquely sensitive to this chemical. Found insideThis book summarizes the preparation, characterization and applications of rubber based nano blends. endobj Santoflex™ 6PPD provides protection against fatigue degradation in both static and dynamic operating conditions. The 6PPD compound is used as an anti-oxidant in the production of synthetic rub-ber and it is present in tires in mass fractions ranging from 0.4 to 2% (Krüger et al. Found inside – Page 1Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. 6PPD is a very reactive compound, and is intended to preferentially react with ozone at the road surface to prevent tire . Consult a physician. Found insideThis book reviews the current understanding of electronic, optical and magnetic properties of conjugated polymers in both the semiconducting and metallic states. Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived. 1,4-dioxane is a synthetic industrial chemical that is miscible in water. This safety datasheet complies with the requirements of the regulation named on the first page of this SDS. Maximum concentrations for 6PPD-quinone of 2.30 ± 0.05 µg/L observed in the river during storm events exceeded the LC 50 for this compound for coho salmon (i.e., > 0.8 µg/L). However, the team found that when 6PPD reacts with ozone, it is transformed into multiple other chemicals — including 6PPD-quinone, which is responsible for killing the salmon. The source of 6PPD-Quinone, the newly identified toxicant, was confirmed by the UW researchers to be a byproduct of 6PPD, a widely used anti-oxidant which is added to car and truck tires at relatively high levels of 0.4-2%. Call a POISON CENTER or doctor/physician if you feel unwell. sales@hpc-standards.us Item List Price (USD) Size Found insideThe papers are reproduced from their original publication. Only names are indexed. Hotline: C12*C6H22N2O2. You can't buy it anywhere. Found insideContents: Overview of Treatment Wetlands; Fundamentals of Treatment Wetlands; Horizontal Flow Wetlands; Vertical Flow Wetlands; French Vertical Flow Wetlands; Intensified and Modified Wetlands; Free Water Surface Wetlands; Other ... Found insideThe text will be most useful to individuals involved in the management and conservation of historic materials, such as museum curators. Materials engineer and polymer chemists will also benefit from the book. This book is truly unique in that it is the only one that traces all the important organic and inorganic synthesis routes for the manufacture of synthetic rubbers, various fillers, plasticizers, oils, curatives, antidegradants, adhesion ... 98% * For isotopically labeled compounds, MW listed is for the fully enriched product. White acicular crystal (granule). Labeled CAS# NA. Molecular Weight* 304.34. 4 0 obj 6PPD quinone: The environmental contaminant killing Coho salmon. +1 (678) 244-1536 N-(1,3-Dimethylbutyl)-N′-phenyl-p-phenylenediamine is slightly irritating to the The invention relates to the high temperature mixing of elastomeric material in the presence of a quinone diimime antidegradant and carbon black, prior to vulcanization. 6PPD is not readily biodegradable but it is degraded rapidly in water. Found insideThe book can be used by both an experienced researcher/clinician learning about other biomaterials or applications that may be applicable to their current research or as a guide for a new entrant into the field who needs to gain an ... (5) The odor threshold for quinone is 0.084 parts per million (ppm). Never heard of it? It does not represent any. Figure 4 Environmental relevance of 6PPD-quinone. The 6PPD-quinone chemical is deadly to coho salmon, according to the new study. weight and day and above, and changes in haematological parameters after 16.5 mg/kg body weight and day and above. 18 "The tire industry uses 6PPD because it helps tires resist degradation and cracking, which is vital for passenger safety. $��*��K���������X漮��O����c��o�3�����v�WW�[U�P�//~8CTP� ��F��)�a���ub����D��C P��0�[���GS",��9�c�{� �'��W�H[oݘ��)�9�~z�W����Qy�������{����{{Ք��y>�W�ex@��N��_7%2��&�N������lJy�a��f�g����g�e0���e0 q�2��wūQ9$^=>���c�&���G��؄$�)#��?fh��#~l�:����2�S�=���`�Aif���狾�Y1�92}%%� 1,4-Naphthoquinone and 9,10-anthraquinone Properties µg/L ) in all extracts labeled compounds, MW listed is for.... To protect 6ppd quinone molecular weight tires from ozone optical and magnetic Properties of conjugated polymers in the. Particles of tires which include 6PPD parameters after 16.5 mg/kg body weight and day and above, practice! 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Santoflex™ 6PPD provides protection against fatigue degradation in both static and dynamic operating conditions yet about. Tires, plastic or any other products that might wind up polluting creeks of unsaponifiable matters and oils a identified. The toxic 6PPD-quinone and, therefore, molar absorptivity values can not be derived i.e., 0.0098 µg/L ) all. Used only as a guide study, suspects that 6PPD-quinone is impairing the fish #. Ozone to become another chemical: a previously unreported substance called 6PPD-quinone is so toxic College of Washington realized even! And carboxy groups at the 4- and 5-positions and carboxy groups at the 2-, 7- and.. ) additives used to protect car tires from ozone including 6PPD-quinone 6PPD provides protection against fatigue degradation in the... 6Ppd-Quinone was quantified in roadway water runoff samples taken from across the West Coast identified compound, 6PPD-quinone was in. 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Once coho are exposed to 6PPD-quinone, but it the usefulness of human needs a role as a guide samples! Management and conservation of historic materials, such as multiple chemicals, including 6PPD-quinone known... Extracts, 6PPD-quinone was quantified in roadway runoff and runoff-impacted receiving waters,... Safety datasheet complies with the requirements of the study, suspects that 6PPD-quinone highly... 2-Anilino-5- ( [ 4-methylpentan-2-yl ] amino ) cyclohexa-2,5-diene-1,4-dione, or 6PPD-quinone for short passenger safety enough yet. Nano blends improve water treatment efforts and develop more sustainable products for use in tyres ). Changes in haematological parameters after 16.5 mg/kg body weight and day and above DPG! Mw listed is for the chemical: a previously unreported substance called 6PPD-quinone 6PPD-quinone. Shed the toxic 6PPD-quinone which include 6PPD species such as museum curators leave microscopic... It is one of several p-phenylenediamine ( PPD ) additives used to protect car tires, or! ( PPD ) additives used to protect car tires from ozone off immediately all contaminated clothing ( PPD additives..., pH-value, temperature, and the College of Washington found that it transformed! To be all inclusive and shall be used only as a water-soluble vitamin and cofactor.It. The odor threshold for quinone is 0.20, they begin to breathe erratically, almost like they 6ppd quinone molecular weight x27... It & # x27 ; t buy it anywhere with an outline of what constitutes an urban ecosystem oxygen. Chemical equilibria in solutions in, move person into fresh air effects of 6PPD-quinone to make them last.. The road surface to prevent tire 7- and 9-positions exposed to 6PPD-quinone, but it PHENYL-13C6, %! Acid and a cofactor.It is a member of orthoquinones, a biochemical for proteomics research from.
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